Yes there is such a thing. It is an advanced technique, and over the years of our marriage, my husband and I have been able to achieve this. The basis of the male multi-orgasm is absolute penile control, and an almost less-is-more approach to basic sex.
This is how we go about it.
My signal to Velvet that he's in for a good time is when he comes home and finds me wearing stockings and heels and nothing else besides my jewelry. I greet him with a kiss, and a glass of wine to help him loosen up and relax while I undress him, right there in the kitchen. The next stop is our bedroom -- the technique requires a bit of room; the sofa won't work, so it's our king-sized mattress.
To do it, we want to slowly coax Hubby into a totally sexual state, a plane which is almost a higher level of consciousness. There is no rush; this is the total opposite of wham-bam-thank-you-ma'am. Extended foreplay, titfucking, LOTS of oral. I'm taking my time as I suck him off, we might even go into a sixty-nine. The goal is for him to cum, of course, but without a lot of forceful fuck action. This means no wrist and hand action while I'm blowing him; I'm not jacking him off into my mouth or on my tits.
The idea is to get him to cum without even thrusting his hips. I let Velvet cum in my mouth, of course, and swallow it all. This first cum is to ensure that he'll be harder for a longer period of time, the second time around. I hold his cock in my mouth - deep throat - until he's finished ejaculating, and then I keep him there, keep sucking up and down. I want to keep him hard, or at least suck him back from a state of semi-softness to full erection.
Hubby's second cumming is what I'm concentrating on. Now is the time for advanced blowjob techniques; butterfly licks all up and down the sensitive underside, working my lips and tongue all about the rim, nibbling the special little 'secret spot' where the base of his cock joins his ballsack.